Vol.28 No.4(3) [2006]

New Developments in solvent reduced Wittig olefination reactions with stabilized Phosphoranes

Thies THIEMANN, Masataka WATANABE and Jesus INIESTA

[ABSTRACT ]

Wittig olefination reactions under solventless and solvent-reduced reaction conditions are discussed. The authors have found that fluorobenzaldehydes such as pentafluorobenzaldehyde react even with the stabilized acetylmethylidenetriphenyl- and benzoylmethylidenetriphenylphosphoranes in solventless reaction systems.